Electrochemistry
Alkenes (Overview)
 
← Back to Alkenes
  
          | Structure & Bonding |     
                             - unsaturated: contain C=C 
            - C atoms in C=C are sp2 hybridised 
            - non-polar 
            - simple molecular structures consisting of alkene molecules held together by weak VDW forces 
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           | Physical Properties |     
                             - relatively low mp/bp 
            - mp/bp increases with increasing molar mass 
            - trans isomer has higher mp than cis isomer due to better packing in the solid lattice 
            - insoluble in water; soluble in organic solvents (e.g. CCl4) 
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           | Chemical Properties |     
           |          Alkenes                    - are unsaturated (contain C=C) → undergo addition reaction 
            - have an e– rich region (double bond) → react with electrophiles 
                   → undergo electrophilic addition reactions        |     
           | Main Reaction(s) |     
                             - Electrophilic addition (with X2/ HX/ H2O) 
            - Reduction (with H2) 
            - Oxidation (with KMnO4/ K2Cr2O7) 
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Alkenes (notes)
← Back to Alkenes   Hydrogenation  Type of Reaction: Reduction/ Addition Hydrogenation is NOT an electrophilic addition reaction; the mechanism is solid state catalysed (adsorption) and does not involve an electrophile.   Alkenes do not react... 
  
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Alkanes (overview)
     Structure & Bonding                 saturated: all C atoms are bonded to 4 atoms       all C atom are sp3 hybridised       non-polar       simple molecular structures consisting of alkane molecules held together by weak VDW forces           ... 
  
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Chemical Bonding
Overview   * Covalent bonds are also present in simple molecular structures. However, they are not broken during physical reactions (e.g. boiling, melting)   For questions related to Chemical Bonding:  Determine the type of substance (metal/... 
  
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H1 Chemistry Syllabus (2008)
PHYSICAL CHEMISTRY  1. ATOMS, MOLECULES AND STOICHIOMETRY • Relative masses of atoms and molecules • The mole, the Avogadro constant • The calculation of empirical and molecular formulae • Reacting masses and volumes (of solutions and gases) 2.... 
  
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Introduction To Organic Chemistry : 12.5 Organic Reaction
 TYPE OF CLEAVAGE : 2 type of bond cleavage:- Hemolytic cleavageHeterolytic cleavage  Hemolytic cleavage The breaking of a single (two-electron) bond in which one electron remains on each of the atoms. Also known as free-radical reaction; homolysis. ... 
Electrochemistry