Electrochemistry
Alkenes (Overview)
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Structure & Bonding |
- unsaturated: contain C=C
- C atoms in C=C are sp2 hybridised
- non-polar
- simple molecular structures consisting of alkene molecules held together by weak VDW forces
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Physical Properties |
- relatively low mp/bp
- mp/bp increases with increasing molar mass
- trans isomer has higher mp than cis isomer due to better packing in the solid lattice
- insoluble in water; soluble in organic solvents (e.g. CCl4)
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Chemical Properties |
Alkenes - are unsaturated (contain C=C) → undergo addition reaction
- have an e– rich region (double bond) → react with electrophiles
→ undergo electrophilic addition reactions |
Main Reaction(s) |
- Electrophilic addition (with X2/ HX/ H2O)
- Reduction (with H2)
- Oxidation (with KMnO4/ K2Cr2O7)
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Alkenes (notes)
← Back to Alkenes Hydrogenation Type of Reaction: Reduction/ Addition Hydrogenation is NOT an electrophilic addition reaction; the mechanism is solid state catalysed (adsorption) and does not involve an electrophile. Alkenes do not react...
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Alkanes (overview)
Structure & Bonding saturated: all C atoms are bonded to 4 atoms all C atom are sp3 hybridised non-polar simple molecular structures consisting of alkane molecules held together by weak VDW forces ...
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Chemical Bonding
Overview * Covalent bonds are also present in simple molecular structures. However, they are not broken during physical reactions (e.g. boiling, melting) For questions related to Chemical Bonding: Determine the type of substance (metal/...
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H1 Chemistry Syllabus (2008)
PHYSICAL CHEMISTRY 1. ATOMS, MOLECULES AND STOICHIOMETRY • Relative masses of atoms and molecules • The mole, the Avogadro constant • The calculation of empirical and molecular formulae • Reacting masses and volumes (of solutions and gases) 2....
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Introduction To Organic Chemistry : 12.5 Organic Reaction
TYPE OF CLEAVAGE : 2 type of bond cleavage:- Hemolytic cleavageHeterolytic cleavage Hemolytic cleavage The breaking of a single (two-electron) bond in which one electron remains on each of the atoms. Also known as free-radical reaction; homolysis. ...
Electrochemistry